This paper presents a new process for synthesizing a kind of nitrogen doped carbon nanotubes ncnts with primarily a graphitelike structure at n substitutions from flames using npropylamine and nbutylamine as fuels. Boron and nitrogen doped single walled carbon nanotubes as. Enhanced electrochemical capacitance of nitrogendoped. The detailed characterization of the produced materials was performed via atomic force. Ion battery anodes peixun xiong school of materials science and engineering, tianjin key laboratory of composite and functional materials and, tianjin key laboratory of molecular optoelectronic science, tianjin university, tianjin, 300072 p. Highly efficient metalfree growth of nitrogendoped single. Functionalization of nitrogendoped carbon nanotubes with. Sinha ray department of chemical technology, university of johannesburg, doornfontein, 2018 johannesburg, south africa 1 l. To read the fulltext of this research, you can request a copy directly from the authors. Insitu immobilization of fefe3cfe2o3 hollow heteronanoparticles onto nitrogendoped carbon nanotubes towards highefficiency electrocatalytic oxygenirureduction binbin zhang, a tongfei li, a longzhen huang, a yiping ren,a dongmei sun, a huan pang,b jun yang,c, d lin xu,a and yawen tanga a jiangsu key laboratory of new power batteries, school of chemistry and materials science. Doped carbon nanotubes derived from metalorganic frameworks for potassium. Oxygen evolution reaction kinetic barriers on nitrogen. Coville dstnrf centre of excellence in strong materials and.
A simple synthesis of nitrogendoped carbon micro and nanotubes. The thermal properties of carbon nanotubes display a wide range of. Nitrogendoped carbon nanotubes synthesised by pyrolysis of. In this study, we report an approach to synthesize cobaltnitrogen doped carbon nanotubes concnts for high oxygen reduction reaction orr activity by cobalt catalyzed carbonization of biomass chitosan. Ye, 3d composite electrodes for high performance pem fuel cells composed of pt supported on nitrogendoped carbon nanotubes grown on carbon paper, electrochemistry communications, vol. Nitrogen doped cnts ncnts were synthesized using an injectionvertical chemical vapor deposition ivcvd reactor. Unique to the conventional template based lewis acidbase activation. Doped carbon nanotubes embedded with co nanocrystals and their application as cathode material for lis batteries seung. Jan 11, 2017 nitrogendoped porous activated carbon monoliths ndpacms have long been the most desirable materials for supercapacitors.
Nitrogen doped carbon nanotubes ncnts have become a topic of increased importance in the study of carbonaceous materials. Here, nitrogendoped carbon nanotubes cntn were synthesized using exfoliated graphitic carbon nitride functionalized with nickel oxides exgc3n4nixoy. When the ncnts are used as the supercapacitor electrode materials, they exhibit a much larger capacitance than the regular carbon nanotubes cnts. Mechanism of the oxidation and thermal defunctionalization of nitrogendoped carbon nanotubes ncnts was studied. Effects of nitrogendoped multiwalled carbon nanotubes. Nitrogendoped carbon nanotubes ncnts can be produced through five main methods. Nitrogendoped carbon nanotube and graphene materials for. Original research the catalytic role of nitrogendoped. Nitrogen doped carbon nanotubes from organometallic compounds. Synthesis and characterization of nitrogendoped carbon nanotubes. Jan 01, 2021 in this paper, a novel structure of nitrogendoped carbon nanotubesencapsulated cobalt nanoparticles email protected is synthesized by a simple dualtemplate strategy using silica colloid and triblock copolymer polyethylene oxidepolypropylene oxidepolyethylene oxide, peoppopeo, f127 as hard and soft templates, respectively. Phosphorus and phosphorusnitrogen doped carbon nanotubes.
Nitrogen doped carbon nanotubes, with average nitrogen content of about 5 wt. These properties include modified chemical reactivity and modified conductivity and mechanical properties. Nitrogendoped carbon nanotube ncnt oxygen reduction reaction orr abstract nitrogendoped carbon nanotubes ncnts were prepared using a. Pyridinetype in which each n atom is bonded to two carbon atoms. Figure s3c and s3d are real images of the hydrothermal process. Turbation in physical properties of onedimensional ma terials but such. However, to be used effectively, the carbon surface must be modi. Sep 23, 2014 nitrogendoped carbon nanotubes as cathode for lithiumair batteries electrochem commun, 2011, pp. Conclusions although more investigation is needed to identify the type of hydrogen bond with the carbon nanotubes, the preliminary results look encouraging. Since the nitrogen doped nanotube literature relies heavily on that of the nitrogen doped carbon film research, it is. N1, n2 and n3 stand for the pyridinic, pyrrolic and quaternary nitrogen atoms.
Nickel supported on nitrogendoped carbon nanotubes as. In this work, nitrogendoped carbon nanotubes ncnts were prepared by a facile chemical vapor deposition method using fesba15 molecular sieve as the catalyst and different organic amines as carbon source and nitrogen source. The incorporation of n atom into a graphene lattice plane could modulate the local electronic properties, as it could form strong bonds with carbon atoms because of its. Nitrogen doping of single and multiwalled carbon nanotubes is of great interest both fundamentally, to explore the effect of dopants on quasi1d electrical conductors, and for applications such as field emission tips, lithium storage, composites and nanoelectronic devices. Nitrogendoped carbon nanotube and graphene materials.
Pdf pd catalysts supported on bamboolike nitrogendoped. Nitrogendoped porous carbon monoliths from polyacrylonitrile. Phosphorus and phosphorusnitrogen doped carbon nanotubes for ultrasensitive and selective molecular detection. Vertically aligned nitrogendoped carbon nanotubes cnts with modulated nitrogen content have been synthesized in a large scale by using spray pyrolysis.
The observed orr activity of ncnts has been directly attributed to increased nitrogen content and. Synthesis and characterization of nitrogen doped carbon nanotubes. Surface modification of nitrogendoped carbon nanotubes by. Nitrogendoped carbon nanotubes intertwined with porous carbon with enhanced cathode performance in lithiumsulfur batteries tao long, ab fancheng meng, ab bin xu, a yixin zhao, a weilin liu, a xiangfeng wei, a lianxi zheng c and jiehua liu a. Mon nanoparticles with average diameter around 25 nm. Co activation using nitrogendoped carbon nanotubes for. Novel fe3c nanoparticles encapsulated in bamboolike. Oxygen evolution reaction kinetic barriers on nitrogendoped carbon nanotubes lauri partanen, garold murdachaew, and kari laasonen department of chemistry and materials science, aalto university, p. Pdf nitrogen doping of single and multiwalled carbon nanotubes is of great interest both fundamentally, to explore the effect of dopants on quasi1d. Boron and nitrogendoped carbon nanotubes and graphene. An efficient and stable nife selenidesnitrogendoped. Nitrogen doped carbon nanotubes ncnts synthesized by chemical vapor deposition have shown promising orr activity as illustrated by many studies 1519.
Nitrogendoped carbon nanotubepolymer nanocomposites. Nitrogen doped carbon nanotubes ncnt that were prepared by simple microwave pyrolysis of niacin vitamin b3 as noble metal free electrocatalyst for oxygen reduction reaction orr is reported. Synthesis of nitrogendoped carbon nanotubes using injection. Electrocatalytic activity of nitrogen doped carbon. Gan formation would be nitrogendoped multiwall carbon nanotubes cn xmwcnts. Research article enhancement of photocatalytic activity on. Here, we report that vertically aligned nitrogencontaining carbon nanotubes vancnts can act as a metalfree electrode with a much better. Appl nanosci nitrogendoped carbon nanotubes as a metal catalyst support letlhogonolo f. Nitrogendoped carbon nanotubepolymer nanocomposites towards. This arises from the physical and chemical properties that are created when n is embedded in a cnt.
The modified surface energy and chemical activity of n. Carbonylation of nitroaromatics with co is extensively investigated with efficient but precious group 810 metalbased catalysts for the productions of both industrially and academically important chemicals such as isocyanates, formamides, carbamates, ureas and several types of heterocyclic compounds. Nitrogendoped carbon nanotubepolymer nanocomposites for thermoelectric applications different types of conductive nanofillers have been employed to develop cpns, viz. Pdf highly active nitrogendoped carbon nanotubes for. Three different catalysts co, fe, and ni were used to synthesize nitrogendoped cnts ncnts by chemical vapor deposition technique. Figure 2 from cobaltembedded nitrogen doped carbon nanotubes. The largescale practical application of fuel cells will be difficult to realize if the expensive platinumbased electrocatalysts for oxygen reduction reactions orrs cannot be replaced by other efficient, lowcost, and stable electrodes. Nitrogen doping of single and multiwalled carbon nanotubes is of great interest both fundamentally, to explore the effect of dopants on quasi1d electrical conductors, and for applications such. Novel fe 3c nanoparticles encapsulated in bamboolike nitrogen doped carbon nanotubes as highperformance electrocatalyst for zincair battery fang liu,1 xiaolong zhang,1,2 xinquan zhang,1,2 minmin liu,2,z qinsi shao,2 li dong,2,3 wei yan,2,z and jiujun zhang2,z 1school of materials of science and engineering, university of shanghai for science and technology, shanghai 200093.
Nitrogen doped carbon nanotubes ncnts have shown promising performance in a variety of applications. Our newly developed technique has the distinct features of sustainable and widely available niacin as a bifunctional source of both carbon and nitrogen, whereas the iron catalyst is cheap and the. Biomass chitosan derived cobaltnitrogen doped carbon. Pdf nitrogendoped carbon nanotubes as a metal catalyst. Box 16100, fi00076 aalto, finland s supporting information abstract.
Fundamentals and scopes of doped carbon nanotubes towards. These nanotubes have been extensively studied by researchers and have unique chemical, electrical and mechanical properties 2024. Physical properties of carbon nanotubes r saito pdf. The results show that the triplet state has a lower total energy for the zigzag tubes but not the armchair tubes. We have performed atomically resolved electron energyloss spectroscopy to detect individual nitrogen dopants in singlewalled carbon nanotubes and. Structurally different nitrogen doped nanotubes and nanofibers ncnts and n cnfs synthesized by a standard method of decomposing ethyleneammonia. B 2 h 6 has been generally used as the boron source while nh 3 or pyridine is employed as the nitrogen source. Sulfurnitrogen doped multi walled carbon nanotubes composite. By using the mixture of benzylamine and toluene, koo. Nife alloyed nanoparticles encapsulated in nitrogen doped. Nitrogendoped carbon nanotubes as a metal catalyst support. Nitrogendoped carbon nanotubes ncnts were synthesized by pyrolysis of 4pyridine4ylmethylideneaminophenyl ferrocene in a solution of either acetonitrile or toluene as carbon source. Dualtemplate strategy for electrocatalyst of cobalt. Atomic configuration of nitrogendoped singlewalled carbon.
Nitrogendoped multiwalled carbon nanotubes ndmwcnts are modified multiwalled carbon nanotubes mwcnts with enhanced electrical properties that are used in a variety of applications, including fuel cells and sensors. Nitrogen doped carbon nanotubes from organometallic. This article appeared in a journal published by elsevier. Multiwalled, singlewalled and doublewalled carbon nanotubes as well as graphene can be doped with boron and nitrogen. Recently, nitrogen ndoping has been introduced to ensure tunable workfunction, enhanced ntype. It is noteworthy that the triplet state is considerably lower than the singlet in the nitrogen doped carbon nanotubes by 4. Pdf synthesis and characterization of nitrogendoped carbon. Enhanced electrochemical capacitance of nitrogendoped carbon. Considering the presence of covalently bonded nitrogen atoms in these carbon nanostructures, they are promising materials for possible. Surface modification of nitrogendoped carbon nanotubes byozone via atomic layer deposition andrew lushington, jian liu, yongji tang, ruying li, and xueliang suna department of mechanical and materials engineering, university of western ontario, london. Raman characterization of nitrogen doped multiwalled carbon nanotubes volume 772 s.
The objective of this research was to investigate the catalytic role of nitrogendoped carbon nanotubes ncnts in a bioreactor that contained acidithiobacillus ferrooxidans a. Nitrogendoped carbon nanotubes ncnts containing 63%, 73% and 80% pyrrolicn were synthesized and used to evaluate the influence of pyrrolic nitrogen on the physicochemical properties and catalytic activity of pd supported on ncnts pdncnts. The resultant ncnts were demonstrated to show considerably higher orr electrocatalytic activities than undoped cnts in both alkaline and acidic media. Comparative viability studies of pure carbon and nitrogendoped multi walled carbon nanotube with amoeba cells. This study investigates the impact of nitrogen doping on the performance of carbon nanotube cntpolymer nanocomposites for thermoelectric applications. Nitrogendoped carbon nanotubes as a metal catalyst. Nitrogendoped carbon nanotubes with high activity for oxygen. Identification of efficient active sites in nitrogendoped. However, there is much disagreement regarding which n doping sites are most desirable for the reaction. Nitrogendoped carbon nanotubes and graphene composite. Herein, we report that rationally designed nitrogendoped carbon nanotubes ncnts exhibit. Recently, great attentionshave been devoted to the study of nitrogendoped carbon nanotubes. Original research the catalytic role of nitrogendoped carbon.
The morphology, structure and composition of the obtained samples were characterized by a series of analytical techniques. Nitrogendoped carbon nanotubes ncnts have demonstrated great promise as an electrocatalyst alternative to platinum for oxygen reduction reaction orr. There then follows ncnt synthesis techniques, and the resultant doped nanotube morphology and possible growth mechanisms. C was found to be the most favourable condition for ncnt growth. Research article synthesis of nitrogendoped carbon nanotubes.
Pdf nitrogen doping in carbon nanotubes researchgate. Mar, 2021 bamboolike nitrogendoped carbon nanotubes ncnts were used to synthesize supported palladium catalysts 0. Structural and morphological control of aligned nitrogen. Raman characterization of nitrogen doped multiwalled carbon.
Jan 14, 2016 although nitrogendoped carbon nanotubes are a very poor hydrogen oxidation catalyst, as a support, it increases the catalytic performance of nickel nanoparticles by a factor of 33 mass activity. For the hydrothermal process htp we used 50 mg of carbon nanotubes in 1. Doping carbon nanotubes and graphene with boron and nitrogen brings about significant changes in the electronic structure and properties. Nitrogendoped carbon nanotubes as a metal catalyst support letlhogonolo mabena introductioncatalysis plays an important role in the production of many compounds in numerous fields such as fuels and fine chemicals ledoux and phamhuu 2005. Nitrogen doped carbon nanotubes synthesized from aliphatic.
Here, we report an experimental and computational study to identify the efficient active sites in ncnts for orr in alkaline media. Herein, we report that rationally designed nitrogendoped carbon nanotubes ncnts. In the present study, we compared the interaction of ndmwcnt or pristine mwcnt7 with. Structurally different nitrogen doped nanotubes and nanofibers ncnts and ncnfs synthesized by a standard method of decomposing ethyleneammonia. Nitrogendoped carbon nanotubes ncnts were synthesized by pyrolysis of 4pyridine4ylmethylideneaminophenylferrocene in a solution of either acetonitrile or toluene as carbon source. Highly efficient metalfree growth of nitrogendoped. This study describes the application of multiwalled carbon nanotubes that were nitrogendoped during their synthesis nmwcnts. Structural evolution of nitrogendoped carbon nanotubes. Nitrogendoped carbon nanotubes intertwined with porous. Sulfurnitrogen doped multi walled carbon nanotubes. Substitutional heteroatom doping is a promising route to modulate the outstanding material properties of carbon nanotubes and graphene for customized applications. A for pyncnt containing less overall nitrogen, quaternary higher ratio indicates more defects present in the nanotubes. Nitrogendoped cnts ncnts were synthesized using an injectionvertical chemical vapor deposition ivcvd reactor. Electrocatalytic activity of nitrogen doped carbon nanotubes.
We investigate kinetic barriers for the oxygen evolution. Aug, 2008 nitrogendoped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction kuanping gong, 1feng du, zhenhai xia,2 michael durstock,3 liming dai1,4 the largescale practical application of fuel cells will be difficult to realize if the expensive. Cruzsilva e1, lopezurias f, munozsandoval e, sumpter bg, terrones h, charlier jc, meunier v, terrones m. Nitrogen doped carbon nanotubes electrocatalytic activity fuel cells abstract in the present study, nitrogen doped carbon nanotubes ncnts were synthesized using three different aliphatic diamines as nitrogen carbon precursor solutions with varying carbon chain lengths, in order. Tio 2nitrogendoped carbon nanotubes nanocomposites linglingwang, 1 longshen, 2 yihuaili, 1 lupingzhu, 1 jiaowenshen, 1 andlijunwang 1 school of urban development and environment engineering, shanghai second polytechnic university, jinhairoad,shanghai, china shanghai shanshan technology co. Ndoped carbon nanotubes enriched with graphitic nitrogen in. Nitrogendoped carbon nanotubes as a metal catalyst support core. Mechanism of the oxidation and thermal defunctionalization of nitrogen doped carbon nanotubes ncnts was studied. Carbon nanomaterials derived from biomass are considered as important sustainable energy carriers. This study describes the application of multiwalled carbon nanotubes that were nitrogen doped during their synthesis nmwcnts. Nitrogen doped carbon nanotubes electrocatalytic activity morphologies fuel cells abstract nitrogen doped carbon nanotubes ncnts were synthesized by a single step chemical vapor deposition technique using either ferrocene or ironii phthalocyanine as catalyst and pyridine as the carbon and nitrogen precursor. Phosphorus and phosphorusnitrogen doped carbon nanotubes for.
Synthesis and characterization of nitrogendoped carbon. The results show that the mfc with the ncntcc as its cathode exhibits an output power density of 542 mw m 3, greater than that of the mfc with the ptccoated cc cathode. Synthesis of nitrogendoped carbon nitrogen n is a neighboring element of carbon in the periodic table, and its electronegativity 3. Keun park department of materials science and engineering, korea university, anam. Research article synthesis of nitrogendoped carbon. Dresselhaus, physical properties of carbon nanotubes, imperial. Vitamin derived nitrogen doped carbon nanotubes for efficient. Vertically aligned cvd reactors with di erent synthesis mechanisms have been used to produce large quantities in the order of kgh.
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